Issue 44, 2008

Thiazepine moiety-controlled regioselective rearrangements of 7-oxanorbornadiene derivatives

Abstract

We have discovered thiazepine moiety-controlled regioselective skeletal rearrangements of 7-oxanorbornadiene derivatives (2, 7 and 12) with high regioselectivity and/or diastereoselectivity in the presence of Brønsted acid.

Graphical abstract: Thiazepine moiety-controlled regioselective rearrangements of 7-oxanorbornadiene derivatives

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2008
Accepted
12 Sep 2008
First published
01 Oct 2008

Chem. Commun., 2008, 5797-5799

Thiazepine moiety-controlled regioselective rearrangements of 7-oxanorbornadiene derivatives

H. Ding, Y. Zhang, W. Yao, D. Xu and C. Ma, Chem. Commun., 2008, 5797 DOI: 10.1039/B813371A

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