Issue 40, 2008

Control of molecular weight in Ni(ii)-catalyzed polymerizationvia the reaction medium

Abstract

The reaction medium controls polymerization with highly active (κ2-P,O)-phosphinesulfonato nickel methyl complexes to afford polyethylenes ranging from low molecular weight (Mn) branched material to high molecular weight (Mn) strictly linear polymer.

Graphical abstract: Control of molecular weight in Ni(ii)-catalyzed polymerizationvia the reaction medium

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2008
Accepted
14 Aug 2008
First published
16 Sep 2008

Chem. Commun., 2008, 4965-4967

Control of molecular weight in Ni(II)-catalyzed polymerizationvia the reaction medium

D. Guironnet, T. Rünzi, I. Göttker-Schnetmann and S. Mecking, Chem. Commun., 2008, 4965 DOI: 10.1039/B811888D

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