Issue 42, 2008
From the journal:

Chemical Communications

Diborylenetetraaminoperylenes (DIBOTAP): a new class of highly fluorescent functional polycyclic aromatic hydrocarbons with N–B–N units†

Till Riehm,a   Gabriele De Paoli,b   Hubert Wadepohl,a   Luisa De Colab  and  Lutz H. Gade*a  

* Corresponding authors

a Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg, Germany
E-mail: lutz.gade@uni-hd.de

b Physikalisches Institut der Universität Münster, Mendelstraße 7, Münster, Germany

Abstract

A new class of N–B–N functionalized perylenes derived from N,N′,N″,N‴-diborylene-3,4,9,10-tetraaminoperylene (DIBOTAP) is readily accessible via several synthetic routes; they display intense green fluorescence and undergo two electrochemically reversible one-electron oxidation steps at ∼−0.2 V and 0.3 V (vs.SCE).

Graphical abstract: Diborylenetetraaminoperylenes (DIBOTAP): a new class of highly fluorescent functional polycyclic aromatic hydrocarbons with N–B–N units

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Article information

DOI
https://doi.org/10.1039/B811864G
Article type
Communication
Submitted
10 Jul 2008
Accepted
11 Aug 2008
First published
19 Sep 2008

Chem. Commun., 2008, 5348-5350

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Diborylenetetraaminoperylenes (DIBOTAP): a new class of highly fluorescent functional polycyclic aromatic hydrocarbons with N–B–N units

T. Riehm, G. De Paoli, H. Wadepohl, L. De Cola and L. H. Gade, Chem. Commun., 2008, 5348 DOI: 10.1039/B811864G

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