Issue 43, 2008

A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase

Abstract

The two-step spin crossover of a new mononuclear iron(II) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS–LSLS] motif.

Graphical abstract: A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase

Supplementary files

Article information

Article type
Communication
Submitted
09 Jul 2008
Accepted
08 Aug 2008
First published
29 Sep 2008

Chem. Commun., 2008, 5619-5621

A two-step spin crossover mononuclear iron(II) complex with a [HS–LS–LS] intermediate phase

S. Bonnet, M. A. Siegler, J. S. Costa, G. Molnár, A. Bousseksou, A. L. Spek, P. Gamez and J. Reedijk, Chem. Commun., 2008, 5619 DOI: 10.1039/B811746B

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