Issue 42, 2008
From the journal:

Chemical Communications

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids†

Tomoya Miura,a   Keita Ueda,a   Yusuke Takahashia  and  Masahiro Murakami*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, Japan
E-mail: murakami@sbchem.kyoto-u.ac
Fax: +81 75 383 2748
Tel: +81 75 383 2747

Abstract

Allenynes having malonate-based tethers reacted with arylboronic acids in the presence of a rhodium(I) catalyst to sequentially form three carbon–carbon bonds, and arylated bicyclic skeletons were constructed in a stereoselective manner.

Graphical abstract: Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/B810665G
Article type
Communication
Submitted
24 Jun 2008
Accepted
22 Jul 2008
First published
16 Sep 2008

Chem. Commun., 2008, 5366-5368

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Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

T. Miura, K. Ueda, Y. Takahashi and M. Murakami, Chem. Commun., 2008, 5366 DOI: 10.1039/B810665G

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