Issue 41, 2008
From the journal:

Chemical Communications

Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents†

Masaki Dainia  and  Michinori Suginome*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: suginome@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2722
Tel: +81-75-383-2723

Abstract

Three-component coupling of bis(dialkylamino)chloroborane, alkynes and organozirconium reagents proceeded in the presence of palladium catalysts, leading to the formation of stereo-defined alkenylborane derivatives via cis-carboboration of carbon–carbon triple bonds.

Graphical abstract: Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

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Article information

DOI
https://doi.org/10.1039/B809433K
Article type
Communication
Submitted
03 Jun 2008
Accepted
16 Jul 2008
First published
12 Sep 2008

Chem. Commun., 2008, 5224-5226

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Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

M. Daini and M. Suginome, Chem. Commun., 2008, 5224 DOI: 10.1039/B809433K

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