Issue 37, 2008
From the journal:

Chemical Communications

Unusual temperature dependence of salt effects for “on water” Wittig reaction: hydrophobicity at the interface†

Shraeddha Tiwaria  and  Anil Kumar*a  

* Corresponding authors

a Physical Chemistry Division, National Chemical Laboratory, Pune, India
E-mail: a.kumar@ncl.res.in
Fax: +9120 2590 2636
Tel: +9120 2590 2278

Abstract

An unusual variation with temperature of the salt effects in aqueous Wittig reaction is observed, suggesting that hydrophobic acceleration of reactions comprising “on water” reactants is fundamentally different from that for reactions with small non-polar solutes.

Graphical abstract: Unusual temperature dependence of salt effects for “on water” Wittig reaction: hydrophobicity at the interface

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Article information

DOI
https://doi.org/10.1039/B809127G
Article type
Communication
Submitted
29 May 2008
Accepted
16 Jun 2008
First published
28 Jul 2008

Chem. Commun., 2008, 4445-4447

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Unusual temperature dependence of salt effects for “on water” Wittig reaction: hydrophobicity at the interface

S. Tiwari and A. Kumar, Chem. Commun., 2008, 4445 DOI: 10.1039/B809127G

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