Issue 28, 2008
From the journal:

Chemical Communications

Ortho-lithiation of free ferrocenyl alcohols: a new method for the synthesis of planar chiral ferrocene derivatives†

Bernhard J. Ueberbacher,*ab   Herfried Grienglab  and  Hansjörg Webera  

* Corresponding authors

a Institute of Organic Chemistry, Graz University of Technology, Stremayrgasse 16, 8010 Graz, Austria
E-mail: Bernhard.ueberbacher@tugraz.at
Fax: +43 316 873 8740
Tel: +43 316 873 8249

b Research Centre Applied Biocatalysis, Petersgasse 14, 8010 Graz, Austria

Abstract

An ortho-metalation method for free ferrocenyl alcohols has been developed, which allows preparation of planar chiral ferrocene derivatives with high yields and diastereoselectivities.

Graphical abstract: Ortho-lithiation of free ferrocenyl alcohols: a new method for the synthesis of planar chiral ferrocene derivatives

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Article information

DOI
https://doi.org/10.1039/B807895E
Article type
Communication
Submitted
14 May 2008
Accepted
28 May 2008
First published
17 Jun 2008

Chem. Commun., 2008, 3287-3289

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Ortho-lithiation of free ferrocenyl alcohols: a new method for the synthesis of planar chiral ferrocene derivatives

B. J. Ueberbacher, H. Griengl and H. Weber, Chem. Commun., 2008, 3287 DOI: 10.1039/B807895E

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