Issue 22, 2008
From the journal:

Chemical Communications

A rare unsupported iridium(ii) dimer, [IrCl2(CO)2]2†

Sanjib K. Patra,a   S. M. Wahidur Rahaman,a   Moumita Majumdar,a   Arup Sinhaa  and  Jitendra K. Bera*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kanpur, India
E-mail: jbera@iitk.ac.in
Fax: +91-512-2597436
Tel: +91-512-2597336

Abstract

Oxidative additions of dichloromethanes to a diiridium(I) core, bridged by 2-ferrocenyl-1,8-naphthyridines (NP-Fc), provide an iridium(II) dimer, [IrCl2(CO)2(η1-NP-Fc)]2, featuring an unsupported Ir–Ir single bond (2.7121(8) Å).

Graphical abstract: A rare unsupported iridium(ii) dimer, [IrCl2(CO)2]2

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Article information

DOI
https://doi.org/10.1039/B803632B
Article type
Communication
Submitted
03 Mar 2008
Accepted
10 Apr 2008
First published
02 May 2008

Chem. Commun., 2008, 2511-2513

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A rare unsupported iridium(II) dimer, [IrCl2(CO)2]2

S. K. Patra, S. M. W. Rahaman, M. Majumdar, A. Sinha and J. K. Bera, Chem. Commun., 2008, 2511 DOI: 10.1039/B803632B

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