Issue 24, 2008

Activation of P5R5 (R = Ph, Et) by a Rh-β-diketiminate complex

Abstract

(NacNac)Rh(C8H14)(N2) reacts with P5R5 to give complexes of formula (NacNac)Rh(P5R5) (R = Ph, Et); in the former species inversion of a P atom of P5Ph5 allows coordination to a Rh(I) centre, whereas in the later species a P–P bond undergoes oxidative addition to give a formally Rh(III) species.

Graphical abstract: Activation of P5R5 (R = Ph, Et) by a Rh-β-diketiminate complex

Supplementary files

Article information

Article type
Communication
Submitted
26 Feb 2008
Accepted
12 Mar 2008
First published
11 Apr 2008

Chem. Commun., 2008, 2779-2781

Activation of P5R5 (R = Ph, Et) by a Rh-β-diketiminate complex

S. J. Geier and D. W. Stephan, Chem. Commun., 2008, 2779 DOI: 10.1039/B803277G

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