We have demonstrated that the unacknowledged presence of almost 30% diene impurity in some commercial phosphate monomers had not only a significant effect on the molecular structure (topology) of a series of synthesized polymers but the instability of the ester functionalities during these polymerizations resulted in unexpectedly complex co-polymer chemistry.
L. Grøndahl, S. Suzuki and E. Wentrup-Byrne, Chem. Commun., 2008, 3314 DOI: 10.1039/B803223H
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