Issue 25, 2008
From the journal:

Chemical Communications

A surfactant-assisted preparation of well dispersed rhodiumnanoparticles within the mesopores of AlSBA-15: characterization and use in catalysis†‡

Maya Boutros,ab   Audrey Denicourt-Nowicki,c   Alain Roucoux,c   Léon Gengembre,d   Patricia Beaunier,e   Antoine Gédéonab  and  Franck Launay*ab  

* Corresponding authors

a UPMC Univ Paris 06, UMR 7142, Systèmes Interfaciaux à l’Echelle Nanométrique, F-75005 Paris, France

b CNRS, UMR 7142, Systèmes Interfaciaux à l’Echelle Nanométrique, F-75005 Paris, France
E-mail: franck.launay@upmc.fr
Fax: +33 1 44 27 55 36
Tel: +33 1 44 27 59 38

c Equipe Chimie Organique et Supramoléculaire, CNRS-UMR 6226 “Sciences chimiques de Rennes”, Ecole Nationale Supérieure de Chimie de Rennes, Avenue du Gal Leclerc, F-35700 Rennes, France

d Unité de Catalyse et de Chimie du Solide, CNRS-UMR 8181, Université des Sciences et Technologies de Lille, Bât. C3, F-59655 Villeneuve d’Ascq, France

e UPMC Univ Paris 06, UMR 7609, Laboratoire de Réactivité de Surface, F-75005 Paris, France

Abstract

Well dispersed and efficient Rh(0) hydrogenation catalysts were obtained by the reduction of Rh(III)-exchanged mesoporous aluminosilicates by sodium borohydride in the presence of N,N-dimethyl-N-cetyl-N-(2-hydroxyethyl) ammonium chloride.

Graphical abstract: A surfactant-assisted preparation of well dispersed rhodium nanoparticles within the mesopores of AlSBA-15: characterization and use in catalysis

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Article information

DOI
https://doi.org/10.1039/B802548G
Article type
Communication
Submitted
14 Feb 2008
Accepted
10 Mar 2008
First published
15 Apr 2008

Chem. Commun., 2008, 2920-2922

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A surfactant-assisted preparation of well dispersed rhodium nanoparticles within the mesopores of AlSBA-15: characterization and use in catalysis

M. Boutros, A. Denicourt-Nowicki, A. Roucoux, L. Gengembre, P. Beaunier, A. Gédéon and F. Launay, Chem. Commun., 2008, 2920 DOI: 10.1039/B802548G

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