Issue 13, 2008

Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

Abstract

A direct, mild and efficient trifluoromethylation of primary and secondary phosphines is achieved with easily accessible, cheap hypervalent iodine compounds acting as electrophilic CF3-transfer reagents.

Graphical abstract: Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

Supplementary files

Article information

Article type
Communication
Submitted
25 Jan 2008
Accepted
20 Feb 2008
First published
03 Mar 2008

Chem. Commun., 2008, 1575-1577

Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(III)–CF3 reagents

P. Eisenberger, I. Kieltsch, N. Armanino and A. Togni, Chem. Commun., 2008, 1575 DOI: 10.1039/B801424H

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