Synthesis, electronic properties and electropolymerisation of EDOT-capped σ3-phospholes

Vincent Lemau de Talancé; Muriel Hissler; Ling-Zhi Zhang; Tamás Kárpáti; László Nyulászi; Dolores Caras-Quintero; Peter Bäuerle; Régis Réau

doi:10.1039/B801335G

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Synthesis, electronic properties and electropolymerisation of EDOT-capped σ³-phospholes†

Vincent Lemau de Talancé,^a Muriel Hissler,*^a Ling-Zhi Zhang,^a Tamás Kárpáti,^b László Nyulászi,*^b Dolores Caras-Quintero,^c Peter Bäuerle*^c and Régis Réau*^a

Author affiliations

* Corresponding authors

^a Sciences Chimiques, UMR 6226 CNRS-Université de Rennes 1, Campus de Beaulieu, Rennes Cedex, France
E-mail: muriel.hissler@univ-rennes1.fr, regis.reau@univ-rennes1.fr

^b Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Szt Gellért tér 4, Budapest, Hungary
E-mail: nyulaszi@mail.bme.hu

^c Institute of Organic Chemistry II and Advanced Materials, Ulm University, Albert-Einstein-Allee 11, Ulm, Germany

Abstract

EDOT-capped σ³-phosphole self-rigidifies due to an unprecedented P–O interaction and can be electropolymerised affording functionalizable polymers.

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Article information

DOI: https://doi.org/10.1039/B801335G
Article type: Communication
Submitted: 25 Jan 2008
Accepted: 04 Mar 2008
First published: 04 Apr 2008

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Chem. Commun., 2008, 2200-2202

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Synthesis, electronic properties and electropolymerisation of EDOT-capped σ³-phospholes

V. Lemau de Talancé, M. Hissler, L. Zhang, T. Kárpáti, L. Nyulászi, D. Caras-Quintero, P. Bäuerle and R. Réau, Chem. Commun., 2008, 2200 DOI: 10.1039/B801335G

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