Issue 28, 2008
From the journal:

Chemical Communications

Cerium(iv)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core structure†

Xiao-Yi Yi,a   Herman H. Y. Sung,a   Ian D. Williamsa  and  Wa-Hung Leung*a  

* Corresponding authors

a Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
E-mail: chleung@ust.hk
Fax: +852 2358-1594
Tel: +852 2358-7360

Abstract

Interaction of [Ce(LOEt)2(NO3)2] (LOEt− = [Co(η5-C5H5){P(O)(OEt)2}3]−) with (NH4)6[Mo7O24] in water affords the cerium(IV)-containing oxomolybdenum cluster [H4(CeLOEt)6Mo9O38], which exhibits a unique Ce6Mo9O38 core structure.

Graphical abstract: Cerium(iv)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core structure

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Article information

DOI
https://doi.org/10.1039/B800176F
Article type
Communication
Submitted
08 Jan 2008
Accepted
29 Apr 2008
First published
11 Jun 2008

Chem. Commun., 2008, 3269-3271

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Cerium(IV)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core structure

X. Yi, H. H. Y. Sung, I. D. Williams and W. Leung, Chem. Commun., 2008, 3269 DOI: 10.1039/B800176F

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