Issue 8, 2008
From the journal:

Chemical Communications

Simple rhodium–chlorophosphine pre-catalysts for the ortho-arylation of phenols†

Robin B. Bedford,*a   Michael Betham,a   Andrew J. M. Caffyn,*b   Jonathan P. H. Charmant,a   Lesley C. Lewis-Alleyne,ab   Philip D. Long,a   Dorian Polo-Cerónac  and  Sanjiv Prashar*c  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock’s Close, Bristol, UK
E-mail: r.bedford@bristol.ac.uk

b Department of Chemistry, The University of the West Indies, St Augustine, Trinidad and Tobago

c Departamento de Química Inorgánica y Analítica, Universidad Rey Juan Carlos, Tulipán; s/n, Móstoles, Madrid, Spain

Abstract

Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.

Graphical abstract: Simple rhodium–chlorophosphine pre-catalysts for the ortho-arylation of phenols

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Article information

DOI
https://doi.org/10.1039/B718128K
Article type
Communication
Submitted
23 Nov 2007
Accepted
14 Dec 2007
First published
10 Jan 2008

Chem. Commun., 2008, 990-992

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Simple rhodium–chlorophosphine pre-catalysts for the ortho-arylation of phenols

R. B. Bedford, M. Betham, A. J. M. Caffyn, J. P. H. Charmant, L. C. Lewis-Alleyne, P. D. Long, D. Polo-Cerón and S. Prashar, Chem. Commun., 2008, 990 DOI: 10.1039/B718128K

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