Issue 47, 2007
From the journal:

Chemical Communications

Low valent phosphorus in the molecular anions [P5Se12]5− and β-[P6Se12]4−: phase change behavior and near infrared second harmonic generation†

In Chung,ab   Joon I. Jang,c   Matthew A. Gave,a   David P. Welikya  and  Mercouri G. Kanatzidis*ab  

* Corresponding authors

a Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA

b Department of Chemistry, Northwestern University, Evanston, IL 60208, USA
E-mail: m-kanatzidis@northwestern.edu
Fax: +1 847 491 5937
Tel: +1 847 467 1541

c Department of Physics and Astronomy, Northwestern University, Evanston, IL 60208, USA

Abstract

The caesium salts of the novel molecular anions [P5Se12]5− and [P6Se12]4− are phase change materials and exhibit near infrared, non-linear optical second harmonic generation; [P5Se12]5− is a coordination complex with an octahedral P3+ center chelated by two [P2Se6]4− ligands whereas [P6Se12]4− features a [P2]4+ dimer chelated by two [P2Se6]4− ligands.

Graphical abstract: Low valent phosphorus in the molecular anions [P5Se12]5− and β-[P6Se12]4−: phase change behavior and near infrared second harmonic generation

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Article information

DOI
https://doi.org/10.1039/B714301J
Article type
Communication
Submitted
17 Sep 2007
Accepted
11 Oct 2007
First published
12 Nov 2007

Chem. Commun., 2007, 4998-5000

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Low valent phosphorus in the molecular anions [P5Se12]5− and β-[P6Se12]4−: phase change behavior and near infrared second harmonic generation

I. Chung, J. I. Jang, M. A. Gave, D. P. Weliky and M. G. Kanatzidis, Chem. Commun., 2007, 4998 DOI: 10.1039/B714301J

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