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Issue 44, 2007
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Yttrium metallocene borane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C5Me5)2Y[η3-C3H4(BC8H14)]} and {(C5Me5)2Y(μ-H)2BC8H14}

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Abstract

(C5Me5)2Y(η3-C3H5) reacts with 9-borabicyclo[3.3.1]nonane, 9-BBN, to form single crystals containing both a borane-substituted allyl complex, (C5Me5)2Y[η3-C3H4(BC8H14)], and a borohydride, (C5Me5)2Y(μ-H)2BC8H14, that can be synthesized directly from 9-BBN and the yttrium hydride, [(C5Me5)2YH]x.

Graphical abstract: Yttrium metallocene borane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C5Me5)2Y[η3-C3H4(BC8H14)]} and {(C5Me5)2Y(μ-H)2BC8H14}

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Publication details

The article was received on 28 Jun 2007, accepted on 06 Sep 2007 and first published on 26 Sep 2007


Article type: Communication
DOI: 10.1039/B709841C
Citation: Chem. Commun., 2007,0, 4662-4664
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    Yttrium metallocene borane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C5Me5)2Y[η3-C3H4(BC8H14)]} and {(C5Me5)2Y(μ-H)2BC8H14}

    W. J. Evans, S. E. Lorenz and J. W. Ziller, Chem. Commun., 2007, 0, 4662
    DOI: 10.1039/B709841C

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