Issue 41, 2007
From the journal:

Chemical Communications

Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion†

Motoi Kawatsura,*a   Fumio Ata,a   Shuichi Hayasea  and  Toshiyuki Itoh*a  

* Corresponding authors

a Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, Japan
E-mail: kawatsur@chem.tottori-u.ac.jp, titoh@chem.tottori-uac.jp
Fax: +81 857 31 5179
Tel: +81 857 31 5179

Abstract

In the RuCl2(p-cymene)/PPh3 catalysed regioselective allylic alkylation of monosubstituted allyl acetates with malonate anion, the selective substitution at the position originally substituted with acetate was observed.

Graphical abstract: Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion

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Article information

DOI
https://doi.org/10.1039/B709218K
Article type
Communication
Submitted
18 Jun 2007
Accepted
30 Jul 2007
First published
10 Aug 2007

Chem. Commun., 2007, 4283-4285

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Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion

M. Kawatsura, F. Ata, S. Hayase and T. Itoh, Chem. Commun., 2007, 4283 DOI: 10.1039/B709218K

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