Competitive O–H and C–H oxidative addition of CH3OH to rhodium(II) porphyrins

Shan Li; Weihong Cui; Bradford B. Wayland

doi:10.1039/B708032H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Competitive O–H and C–H oxidative addition of CH₃OH to rhodium(ii) porphyrins

Shan Li,^a Weihong Cui^a and Bradford B. Wayland*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA
E-mail: wayland@sas.upenn.edu
Fax: 215573 6743
Tel: 215898 8633

Abstract

Rhodium(II) porphyrins react with CH₃OH in benzene by alternate mechanisms that give H–CH₂OH and H–OCH₃ bond activation in different methanol concentration regimes which is a rare example of transition metal reactivity with methanol.

Download options Please wait...

Article information

DOI: https://doi.org/10.1039/B708032H
Article type: Communication
Submitted: 05 Jun 2007
Accepted: 17 Aug 2007
First published: 29 Aug 2007

Download Citation

Chem. Commun., 2007, 4024-4025

Permissions

Request permissions

Competitive O–H and C–H oxidative addition of CH₃OH to rhodium(II) porphyrins

S. Li, W. Cui and B. B. Wayland, Chem. Commun., 2007, 4024 DOI: 10.1039/B708032H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications