Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes

Doris Pun; Emil Lobkovsky; Paul J. Chirik

doi:10.1039/B704941B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N₂ complexes†

Doris Pun,^a Emil Lobkovsky^a and Paul J. Chirik*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY, USA
E-mail: pc92@cornell.edu
Fax: +1 607-255-4137
Tel: +1 607-254-4538

Abstract

Catalytic dehydrogenation of R₂NHBH₃ (R = Me, H) promoted by a family of bis(cyclopentadienyl)titanium and bis(indenyl)zirconium compounds is reported; structure–reactivity relationships as a function of cyclopentadienyl and indenyl substituents have been examined.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B704941B
Article type: Communication
Submitted: 02 Apr 2007
Accepted: 26 May 2007
First published: 11 Jun 2007

Download Citation

Chem. Commun., 2007, 3297-3299

Permissions

Request permissions

Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N₂ complexes

D. Pun, E. Lobkovsky and P. J. Chirik, Chem. Commun., 2007, 3297 DOI: 10.1039/B704941B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications