Issue 21, 2007
From the journal:

Chemical Communications

Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin†

Sébastien Richeter,*a   Aurélie Hadj-Aïssa,a   Céline Taffin,a   Arie van der Leeb  and  Dominique Leclercqa  

* Corresponding authors

a Institut Charles Gerhardt, UM2, CNRS, équipe CMOS, CC 007, Université Montpellier 2, Place Eugène Bataillon, Montpellier Cedex 05, France
E-mail: Sebastien.Richeter@univ-montp2.fr

b Institut Européen des Membranes, UM2, CNRS, ENSCM, CC 045, Université Montpellier 2, Place Eugène Bataillon, Montpellier Cedex 05, France

Abstract

The functionalisation of two neighboring β-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene ligand, the subsequent metallation of this external coordination site by palladium(II) and the structural characterisation of the resulting compounds are presented.

Graphical abstract: Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin

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Article information

DOI
https://doi.org/10.1039/B704681B
Article type
Communication
Submitted
28 Mar 2007
Accepted
19 Apr 2007
First published
01 May 2007

Chem. Commun., 2007, 2148-2150

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Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin

S. Richeter, A. Hadj-Aïssa, C. Taffin, A. van der Lee and D. Leclercq, Chem. Commun., 2007, 2148 DOI: 10.1039/B704681B

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