Issue 27, 2007

Supported ionic liquidcatalyst (Pd-SILC) for highly efficient and recyclable Suzuki–Miyaura reaction

Abstract

Highly efficient Suzuki–Miyaura coupling of aryl halides with arylboronic acid was realized in 50% aqueous ethanol at room temperature employing Pd(OAc)2 immobilized in diethylaminopropylated (NDEAP) alumina pores with the aid of [bmim]PF6, which enabled recycle use up to five times in 95% average yield and turnover number of two million.

Graphical abstract: Supported ionic liquid catalyst (Pd-SILC) for highly efficient and recyclable Suzuki–Miyaura reaction

Article information

Article type
Communication
Submitted
19 Mar 2007
Accepted
18 Apr 2007
First published
01 May 2007

Chem. Commun., 2007, 2838-2840

Supported ionic liquid catalyst (Pd-SILC) for highly efficient and recyclable Suzuki–Miyaura reaction

H. Hagiwara, K. H. Ko, T. Hoshi and T. Suzuki, Chem. Commun., 2007, 2838 DOI: 10.1039/B704098A

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