Issue 26, 2007

Turning up the spin, turning on single-molecule magnetism: from S = 1 to S = 7 in a [Mn8] cluster vialigand induced structural distortion

Abstract

The spin ground state of a [MnIII6MnII2] cluster has been deliberately switched from S = 1 to S = 7 upon designed ligand substitution.

Graphical abstract: Turning up the spin, turning on single-molecule magnetism: from S = 1 to S = 7 in a [Mn8] cluster via ligand induced structural distortion

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
01 Mar 2007
Accepted
13 Apr 2007
First published
03 May 2007

Chem. Commun., 2007, 2738-2740

Turning up the spin, turning on single-molecule magnetism: from S = 1 to S = 7 in a [Mn8] cluster via ligand induced structural distortion

C. J. Milios, R. Inglis, A. Vinslava, A. Prescimone, S. Parsons, S. P. Perlepes, G. Christou and E. K. Brechin, Chem. Commun., 2007, 2738 DOI: 10.1039/B703089D

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