Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone

Anne-Marie Alexander; Marc Bria; Gunther Brunklaus; Stuart Caldwell; Graeme Cooke; James F. Garety; Shanika G. Hewage; Yann Hocquel; Niall McDonald; Gouher Rabani; Georgina Rosair; Brian O. Smith; Hans Wolfgang Spiess; Vincent M. Rotello; Patrice Woisel

doi:10.1039/B703070C

Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone†

Anne-Marie Alexander,^a Marc Bria,^b Gunther Brunklaus,^c Stuart Caldwell,^a Graeme Cooke,*^a James F. Garety,^a Shanika G. Hewage,^a Yann Hocquel,^d Niall McDonald,^a Gouher Rabani,^a Georgina Rosair,^d Brian O. Smith,^e Hans Wolfgang Spiess,^c Vincent M. Rotello^f and Patrice Woisel^b

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* Corresponding authors

^a WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, UK
E-mail: graemec@chem.gla.ac.uk

^b Laboratoire de Chimie Organique et Macromoléculaire & CCM-RMN Lille 1, Université des Sciences et Technologies de Lille, Villeneuve d'Ascq, France

^c Max-Planck-Institut für Polymerforschung, Postfach 3148, Mainz, Germany

^d Chemistry, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh, UK

^e IBLS, University of Glasgow, Glasgow, UK

^f Department of Chemistry, University of Massachusetts at Amherst, Amherst, MA 01002, USA

Abstract

A ferrocene-functionalised ureidopyrimidinone has been synthesised that can signal the solvent-induced tautomerism of the dimeric 4[1H]-pyrimidinone form to the monomeric 6[1H]-pyrimidinone form.

Chemical Communications

Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone†

Abstract

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Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone

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