Fine-tuning of a ferrocene|porphyrin|ITO redox cascade for efficient sequential electron transfer commenced by an S2 photoexcited special-pair mimic

Mitsuhiko Morisue; Dipak Kalita; Noriko Haruta; Yoshiaki Kobuke

doi:10.1039/B700632B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Fine-tuning of a ferrocene|porphyrin|ITO redox cascade for efficient sequential electron transfer commenced by an S₂ photoexcited special-pair mimic†

Mitsuhiko Morisue,‡^a Dipak Kalita,^a Noriko Haruta^a and Yoshiaki Kobuke*^a

Author affiliations

* Corresponding authors

^a Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma, Japan
E-mail: kobuke@ms.naist.jp
Fax: (+81)743-72-6119

Abstract

A systematic series of ferrocene/porphyrin redox cascade architectures was assembled through a slipped-cofacial porphyrin dimer on ITO electrode in optimizing the anodic photocurrent generation to perform the highest quantum yield compared to reported values on ITO electrodes.

Download options Please wait...

Supplementary files

XPS, CV, UV-vis and photocurrent action spectra PDF (1210K)

Article information

DOI: https://doi.org/10.1039/B700632B
Article type: Communication
Submitted: 15 Jan 2007
Accepted: 12 Feb 2007
First published: 07 Mar 2007

Download Citation

Chem. Commun., 2007, 2348-2350

Permissions

Request permissions

Fine-tuning of a ferrocene|porphyrin|ITO redox cascade for efficient sequential electron transfer commenced by an S₂ photoexcited special-pair mimic

M. Morisue, D. Kalita, N. Haruta and Y. Kobuke, Chem. Commun., 2007, 2348 DOI: 10.1039/B700632B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications