Issue 19, 2007
From the journal:

Chemical Communications

New coordination modes at molybdenum for 2-diphenylphosphinoaniline derived ligands

Carl Redshaw,*a   Vernon C. Gibson,b   Mark R. J. Elsegoodc  and  William Cleggd  

* Corresponding authors

a Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, The University of East Anglia, Norwich, UK
E-mail: carl.redshaw@uea.ac.uk
Fax: +44 (0)1603 592003
Tel: +44 (0)1603 593137

b Department of Chemistry, Imperial College, London, UK

c Chemistry Department, Loughborough University, Loughborough, UK

d School of Natural Sciences, The University of Newcastle upon Tyne, UK

Abstract

The complexes [MoCl3(1-N,2-Ph2P-C6H4)2] (1) and {MoCl(Nt-Bu)[1-μ(N),2-(Ph2P)C6H4]}2 (2) have been obtained from the reaction of 2-diphenylphosphinoaniline [1,2-(NH2)(Ph2P)C6H4] with either sodium molybdate [Na2MoO4] (in the presence of Et3N and Me3SiCl) or [MoCl2(Nt-Bu)2(DME)]; the crystal structure of 1 reveals a novel MoNC2PN six-membered conjugated ring system derived from a P–N coupling reaction between two ligands, whilst that of 2 reveals bridging imido/terminal phosphine ligation.

Graphical abstract: New coordination modes at molybdenum for 2-diphenylphosphinoaniline derived ligands

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Article information

DOI
https://doi.org/10.1039/B700158D
Article type
Communication
Submitted
05 Jan 2007
Accepted
29 Jan 2007
First published
16 Feb 2007

Chem. Commun., 2007, 1951-1953

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New coordination modes at molybdenum for 2-diphenylphosphinoaniline derived ligands

C. Redshaw, V. C. Gibson, M. R. J. Elsegood and W. Clegg, Chem. Commun., 2007, 1951 DOI: 10.1039/B700158D

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