Issue 20, 2007

Unusual nickel-mediated C–S cleavage of alkyl and aryl sulfoxides

Abstract

The first examples of transition metal mediated C–S cleavage of sulfoxides containing sp2- and sp3-hybridized carbon bonds attached to the sulfur atom and the first example of a structurally characterized complex featuring an oxygen-bound sulfinyl ligand are presented.

Graphical abstract: Unusual nickel-mediated C–S cleavage of alkyl and aryl sulfoxides

Supplementary files

Article information

Article type
Communication
Submitted
20 Dec 2006
Accepted
01 Feb 2007
First published
22 Feb 2007

Chem. Commun., 2007, 2037-2039

Unusual nickel-mediated C–S cleavage of alkyl and aryl sulfoxides

T. Schaub, M. Backes and U. Radius, Chem. Commun., 2007, 2037 DOI: 10.1039/B618632G

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