Issue 9, 2007
From the journal:

Chemical Communications

Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions†

Matthew L. Maddess,a   Emily Mainetti,a   Youssef Harrak,a   Célia Brancour,a   Priscille Devin,a   Anne-Lise Dhimane,a   Louis Fensterbank*a  and  Max Malacria*a  

* Corresponding authors

a Laboratorie de Chimie Organique, UMR CNRS 7611, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie - Paris 6, Case 229, 4 Place Jussieu, Paris, France
E-mail: fensterb@ccr.jussieu.fr, malacria@ccr.jussieu.fr
Fax: (+33)1-4427-7360

Abstract

Radical cascades employing (dichloromethyl)dimethylsilyl ethers as both a point of radical initiation and termination, allow efficient entry to fused polycyclic cyclopropanes, and are also suitable for the design of other radical processes terminated by β-elimination of chloride.

Graphical abstract: Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions

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Article information

DOI
https://doi.org/10.1039/B618156B
Article type
Communication
Submitted
12 Dec 2006
Accepted
12 Jan 2007
First published
30 Jan 2007

Chem. Commun., 2007, 936-938

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Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions

M. L. Maddess, E. Mainetti, Y. Harrak, C. Brancour, P. Devin, A. Dhimane, L. Fensterbank and M. Malacria, Chem. Commun., 2007, 936 DOI: 10.1039/B618156B

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