Issue 20, 2007
From the journal:

Chemical Communications

Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br–Mg exchange†

Taramatee Ramnial,a   Stephanie A. Taylor,a   Jason A. C. Clyburneab  and  Charles J. Walsbya  

a Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada
E-mail: cwalsby@sfu.ca
Fax: 604 291 3765
Tel: 604 291 4607

b Department of Chemistry, Saint Mary's University, 923 Robie Street, Halifax, Nova Scotia, Canada
E-mail: jason.clyburne@smu.ca
Tel: 902 420-5649

Abstract

Grignard reagents form persistent solutions in phosphonium ionic liquids possessing O-donor anions and these solutions are excellent reaction media for electron transfer processes and transmetallation reactions.

Graphical abstract: Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br–Mg exchange

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Article information

DOI
https://doi.org/10.1039/B617861H
Article type
Communication
Submitted
08 Dec 2006
Accepted
10 Apr 2007
First published
23 Apr 2007

Chem. Commun., 2007, 2066-2068

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Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br–Mg exchange

T. Ramnial, S. A. Taylor, J. A. C. Clyburne and C. J. Walsby, Chem. Commun., 2007, 2066 DOI: 10.1039/B617861H

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