Issue 18, 2007
From the journal:

Chemical Communications

Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization†

Shota Niibayashi,a   Hitoshi Hayakawa,a   Ren-Hua Jina  and  Hideo Nagashima*b  

* Corresponding authors

a Dainippon Ink and Chemicals, Incorporated, 631 Sakado, Sakura, Chiba, Japan

b Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasugakoen Kasuga, Fukuoka, Japan
E-mail: nagasima@cm.kyushu-u.ac.jp
Fax: (+81)92-583-7819

Abstract

Ionic iron complex [(Me3tacn)2Fe2Cl3]+[(Me3tacn)FeCl3]− (1), which is readily soluble in methanol, acted as a powerful catalyst in controlled radical polymerization of styrene and MMA, and showed promising features of removal from the resulting polymers and was reusable after recovery from the crude products.

Graphical abstract: Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization

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Article information

DOI
https://doi.org/10.1039/B617722K
Article type
Communication
Submitted
05 Dec 2006
Accepted
17 Jan 2007
First published
15 Feb 2007

Chem. Commun., 2007, 1855-1857

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Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization

S. Niibayashi, H. Hayakawa, R. Jin and H. Nagashima, Chem. Commun., 2007, 1855 DOI: 10.1039/B617722K

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