Issue 6, 2007
From the journal:

Chemical Communications

The first actinyl cyanide

Jean-Claude Berthet,*a   Pierre Thuérya  and  Michel Ephritikhinea  

* Corresponding authors

a Service de Chimie Moléculaire, DSM, DRECAM, CNRS URA 331, Laboratoire Claude Fréjacques, CEA Saclay, Gif-sur-Yvette, France
E-mail: jean-claude.berthet@cea.fr
Fax: 33 169 08 640
Tel: 33 169 08 60 42

Abstract

Reaction of UO2(OTf)2 with 5 molar equivalents of NEt4CN in acetonitrile led to the formation of the pentacyano uranyl complex [NEt4]3[UO2(CN)5] which is monomeric in the solid state with the five C-coordinated cyanide ions lying in the equatorial plane perpendicular to the linear {UO2} axis.

Graphical abstract: The first actinyl cyanide

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Article information

DOI
https://doi.org/10.1039/B614226E
Article type
Communication
Submitted
02 Oct 2006
Accepted
25 Oct 2006
First published
07 Nov 2006

Chem. Commun., 2007, 604-606

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The first actinyl cyanide

J. Berthet, P. Thuéry and M. Ephritikhine, Chem. Commun., 2007, 604 DOI: 10.1039/B614226E

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