Issue 3, 2007

Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates

Abstract

The regioselectivity in the ruthenium-catalysed allylic alkylation of mono substituted allyl acetates with the malonate anion was highly controlled by Ru3(CO)12 with 2-(diphenylphosphino)benzoic acid, and the linear-type alkylated product was obtained.

Graphical abstract: Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates

Supplementary files

Article information

Article type
Communication
Submitted
26 Sep 2006
Accepted
17 Oct 2006
First published
27 Oct 2006

Chem. Commun., 2007, 298-300

Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates

M. Kawatsura, F. Ata, S. Wada, S. Hayase, H. Uno and T. Itoh, Chem. Commun., 2007, 298 DOI: 10.1039/B614015G

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