Issue 1, 2007
From the journal:

Chemical Communications

Structurally characterized intermediates in the stepwise insertion of CO–ethylene or CO–methyl acrylate into the metal–carbon bond of Pd(ii) complexes stabilized by (phosphinomethyl)oxazoline ligands†

Magno Agostinhoa  and  Pierre Braunstein*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination (UMR 7177 CNRS), Institut de Chimie, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France
E-mail: braunst@chimie.u-strasbg.fr
Fax: +33 390 241 322

Abstract

The initial CO–ethylene or CO–methyl acrylate insertion steps into the Pd–Me bond of methylpalladium(II) complexes with (phosphinomethyl)oxazoline ligands, leading to metallacycles, have been fully characterized, including by X-ray diffraction.

Graphical abstract: Structurally characterized intermediates in the stepwise insertion of CO–ethylene or CO–methyl acrylate into the metal–carbon bond of Pd(ii) complexes stabilized by (phosphinomethyl)oxazoline ligands

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Article information

DOI
https://doi.org/10.1039/B613865A
Article type
Communication
Submitted
25 Sep 2006
Accepted
09 Nov 2006
First published
23 Nov 2006

Chem. Commun., 2007, 58-60

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Structurally characterized intermediates in the stepwise insertion of CO–ethylene or CO–methyl acrylate into the metal–carbon bond of Pd(II) complexes stabilized by (phosphinomethyl)oxazoline ligands

M. Agostinho and P. Braunstein, Chem. Commun., 2007, 58 DOI: 10.1039/B613865A

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