Issue 6, 2007
From the journal:

Chemical Communications

Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes†

Marco Bandini,*a   Fabio Piccinelli,a   Simona Tommasi,a   Achille Umani-Ronchi*a  and  Caterina Ventricia  

* Corresponding authors

a Dipartimento di Chimica “G. Ciamician”, Università di Bologna, Via Selmi 2, Bologna, Italy
E-mail: marco.bandini@unibo.it, achille.umanironchi@unibo.it
Fax: +39 051 2099456
Tel: +39 051 2099509

Abstract

Remarkable generality in scope of DATs/Cu catalysts for enantioselective nitroaldol reaction is described; excellent levels of stereoinduction are recorded for a range of aldehydes (ee 81–99%, 17 examples) and the possibility to employ the present catalytic system as the key step for the preparation of highly functionalized tetrahydro-isoquinolines is demonstrated.

Graphical abstract: Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes

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Article information

DOI
https://doi.org/10.1039/B613019D
Article type
Communication
Submitted
08 Sep 2006
Accepted
17 Oct 2006
First published
07 Nov 2006

Chem. Commun., 2007, 616-618

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Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes

M. Bandini, F. Piccinelli, S. Tommasi, A. Umani-Ronchi and C. Ventrici, Chem. Commun., 2007, 616 DOI: 10.1039/B613019D

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