Issue 5, 2007

Asymmetric total synthesis of martinelline and martinellic acid

Abstract

Herein, we describe the first asymmetric total synthesis of (–)-martinelline ((–)-2) and the second total synthesis of (–)-martinellic acid ((–)-1) by employing a tandem Mukaiyama–Mannich reaction/aminal cyclization as the key step.

Graphical abstract: Asymmetric total synthesis of martinelline and martinellic acid

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2006
Accepted
18 Oct 2006
First published
01 Nov 2006

Chem. Commun., 2007, 504-506

Asymmetric total synthesis of martinelline and martinellic acid

S. Ikeda, M. Shibuya and Y. Iwabuchi, Chem. Commun., 2007, 504 DOI: 10.1039/B611121A

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