Issue 1, 2007
From the journal:

Chemical Communications

Iron–sulfur cluster stability. Kinetics and mechanism of ligand-promoted cluster degradation†

Shu-pao Wu‡a  and  J. A. Cowan*a  

* Corresponding authors

a Evans Laboratory of Chemistry, Ohio State University, 100 West, 18th Ave, Columbus, USA
E-mail: cowan@chemistry.ohio-state.edu

Abstract

Reactivity studies of iron–sulfur cluster proteins with chelating ligands model the reactivity of cluster scaffold proteins such as ISU, and suggest a rate law [kobs = k2[ligand]n/{[ligand]n + KD}] consistent with formation of a pre-reaction complex between the Fe–S protein and one chelate ligand.

Graphical abstract: Iron–sulfur cluster stability. Kinetics and mechanism of ligand-promoted cluster degradation

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Article information

DOI
https://doi.org/10.1039/B610665J
Article type
Communication
Submitted
26 Jul 2006
Accepted
21 Sep 2006
First published
18 Oct 2006

Chem. Commun., 2007, 82-84

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Iron–sulfur cluster stability. Kinetics and mechanism of ligand-promoted cluster degradation

S. Wu and J. A. Cowan, Chem. Commun., 2007, 82 DOI: 10.1039/B610665J

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