Issue 47, 2006
From the journal:

Chemical Communications

Elucidation of the extraordinary 4-membered pyrrole ring-contracted azeteoporphyrinoid as an intermediate in chlorin oxidation†

Tillmann Köpke,a   Maren Pinka  and  Jeffrey M. Zaleski*a  

* Corresponding authors

a Department of Chemistry, Indiana University, Bloomington, IN, U.S.A
E-mail: zaleski@indiana.edu
Fax: +1 (812) 855-8300
Tel: +1 (812) 855-2134

Abstract

Reaction of 2,3-dioxochlorins with benzeneselenic anhydride (BSA) results in the formation of unusual ring-contracted azetine derivatives that further react with BSA to afford porpholactones.

Graphical abstract: Elucidation of the extraordinary 4-membered pyrrole ring-contracted azeteoporphyrinoid as an intermediate in chlorin oxidation

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Article information

DOI
https://doi.org/10.1039/B611567E
Article type
Communication
Submitted
12 Aug 2006
Accepted
19 Sep 2006
First published
06 Oct 2006

Chem. Commun., 2006, 4940-4942

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Elucidation of the extraordinary 4-membered pyrrole ring-contracted azeteoporphyrinoid as an intermediate in chlorin oxidation

T. Köpke, M. Pink and J. M. Zaleski, Chem. Commun., 2006, 4940 DOI: 10.1039/B611567E

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