Issue 45, 2006
From the journal:

Chemical Communications

A series of luminescent lanthanide–cadmium–organic frameworks with helical channels and tubes†

Yan-Qiong Sun,a   Jie Zhanga  and  Guo-Yu Yang*ab  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: ygy@fjirsm.ac.cn
Fax: +86-591-83710051

b State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, P. R. China

Abstract

Lanthanide (Ln) oxides and cadmium (Cd) salts as sources of metals provided the first series of luminescent Ln–Cd–organic frameworks, [LnCd(imdc)(SO4)(H2O)3]·0.5H2O (Ln = Tb, Eu, Dy, Gd, Er, Yb, Y, Nd, Pr; H3imdc = 4,5-imidazoledicarboxylic acid), in which the Ln atoms are linked by imdc ligands with skew coordination orientation, resulting in novel hetero-metallic–organic frameworks with left–/right–handed helical tubes (L1/R1) and channels (L2/R2) along the b axis.

Graphical abstract: A series of luminescent lanthanide–cadmium–organic frameworks with helical channels and tubes

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Article information

DOI
https://doi.org/10.1039/B610892J
Article type
Communication
Submitted
28 Jul 2006
Accepted
12 Sep 2006
First published
03 Oct 2006

Chem. Commun., 2006, 4700-4702

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A series of luminescent lanthanide–cadmium–organic frameworks with helical channels and tubes

Y. Sun, J. Zhang and G. Yang, Chem. Commun., 2006, 4700 DOI: 10.1039/B610892J

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