Issue 39, 2006
From the journal:

Chemical Communications

Enantioselective nitroaldol (Henry) reaction using copper(ii) complexes of (−)-sparteine†

H. Maheswaran,*a   K. Leon Prasanth,a   G. Gopi Krishna,a   K. Ravikumar,b   B. Sridharb  and  M. Lakshmi Kantama  

* Corresponding authors

a IPC Division, Indian Institute of Chemical Technology, Hyderabad, India
E-mail: maheswaran_dr@yahoo.com
Fax: 91 4027160921
Tel: 91 4027193510

b X-ray Crystallography Centre, Indian Institute of Chemical Technology, Hyderabad, India

Abstract

The dichloro[(−)-sparteine-N,N′]copper(II) complex provides Henry adducts with high enantioselectivities (73–97% ee) in Henry reaction between nitromethane and various aldehydes.

Graphical abstract: Enantioselective nitroaldol (Henry) reaction using copper(ii) complexes of (−)-sparteine

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DOI
https://doi.org/10.1039/B610203D
Article type
Communication
Submitted
17 Jul 2006
Accepted
29 Aug 2006
First published
14 Sep 2006

Chem. Commun., 2006, 4066-4068

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Enantioselective nitroaldol (Henry) reaction using copper(II) complexes of (−)-sparteine

H. Maheswaran, K. L. Prasanth, G. G. Krishna, K. Ravikumar, B. Sridhar and M. L. Kantam, Chem. Commun., 2006, 4066 DOI: 10.1039/B610203D

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