Issue 40, 2006
From the journal:

Chemical Communications

Dynamic ligation at the first amine-coordinated iron hydrogenase active site mimic†

Lennart Schwartz,a   Jesper Ekström,b   Reiner Lomoth*a  and  Sascha Ott*a  

* Corresponding authors

a Department of Photochemistry and Molecular Science, Uppsala University, Box 523, Uppsala, Sweden
E-mail: reiner.lomoth@fotomol.uu.se; sascha.ott@fotomol.uu.se
Fax: +46 (0)18 4716844

b Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden

Abstract

The first model of the iron hydrogenase active site has been prepared in which an amine ligand is loosely coordinated to an FeI centre, and can be replaced by a solvent molecule; irrespective of the ligand set, the one electron reduction of both complexes is chemically reversible and is shown to proceed through the same species which features a bridging CO ligand.

Graphical abstract: Dynamic ligation at the first amine-coordinated iron hydrogenase active site mimic

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B608260B
Article type
Communication
Submitted
14 Jun 2006
Accepted
02 Aug 2006
First published
24 Aug 2006

Chem. Commun., 2006, 4206-4208

Permissions

Request permissions

Dynamic ligation at the first amine-coordinated iron hydrogenase active site mimic

L. Schwartz, J. Ekström, R. Lomoth and S. Ott, Chem. Commun., 2006, 4206 DOI: 10.1039/B608260B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements