Issue 24, 2006

A high-nuclearity, beyond “fully reduced” polyoxo(alkoxo)vanadium(iii/iv) cage

Abstract

The solvothermal synthesis, crystal structure and preliminary magnetic studies are reported of the first high nuclearity VIII-based polyoxo(alkoxo)vanadium cage, a VIII16VIV2 complex.

Graphical abstract: A high-nuclearity, beyond “fully reduced” polyoxo(alkoxo)vanadium(iii/iv) cage

Supplementary files

Article information

Article type
Communication
Submitted
10 Apr 2006
Accepted
04 May 2006
First published
18 May 2006

Chem. Commun., 2006, 2560-2562

A high-nuclearity, beyond “fully reduced” polyoxo(alkoxo)vanadium(III/IV) cage

I. S. Tidmarsh, R. H. Laye, P. R. Brearley, M. Shanmugam, E. C. Sañudo, L. Sorace, A. Caneschi and E. J. L. McInnes, Chem. Commun., 2006, 2560 DOI: 10.1039/B605106E

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