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Issue 4, 2006
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Novel one-pot synthesis of 5-alkenyl-15-alkynylporphyrins and their derivatisation to a butadiyne-linked benzoporphyrin dimer

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Abstract

5-Alkenyl-15-alkynylporphyrins have been obtained unexpectedly by [2 + 2] acid-catalyzed condensation of dipyrrylmethane and TMS propynal in addition to 5,15-dialkynylporphyrin, and the unsymmetrical porphyrin can be converted to a butadiyne-linked dimer by selective desilylation of the alkynyl TMS.

Graphical abstract: Novel one-pot synthesis of 5-alkenyl-15-alkynylporphyrins and their derivatisation to a butadiyne-linked benzoporphyrin dimer

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Publication details

The article was received on 29 Sep 2005, accepted on 19 Nov 2005 and first published on 06 Dec 2005


Article type: Communication
DOI: 10.1039/B513848E
Citation: Chem. Commun., 2006,0, 383-385
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    Novel one-pot synthesis of 5-alkenyl-15-alkynylporphyrins and their derivatisation to a butadiyne-linked benzoporphyrin dimer

    H. Yamada, K. Kushibe, T. Okujima, H. Uno and N. Ono, Chem. Commun., 2006, 0, 383
    DOI: 10.1039/B513848E

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