Issue 6, 2006
From the journal:

Chemical Communications

A molecular pinwheel multicopper(i) cluster, [(LS−)6CuI13(S2−)2]3+ with μ4-sulfido, μ3-thiolato and nitrogenligands

Yunho Lee,a   Amy A. Narducci Sarjeanta  and  Kenneth D. Karlin*a  

* Corresponding authors

a Department of Chemistry, John Hopkins University, 3400 North Charles Street, Baltimore, USA
E-mail: karlin@jhu.edu
Fax: +1-410-516-8420
Tel: +1-410-516-8027

Abstract

A copper(I) complex with new N2S thiol ligand transforms to a multicopper(I) cluster, [(LS−)6CuI13(S2−)2]3+ (1); its X-ray structure exhibiting μ4-sulfido and μ3-thiolato coordination is presented and compared to other cuprous thiolato/sulfido clusters including that observed in the copper enzyme nitrous oxide reductase.

Graphical abstract: A molecular pinwheel multicopper(i) cluster, [(LS−)6CuI13(S2−)2]3+ with μ4-sulfido, μ3-thiolato and nitrogen ligands

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Article information

DOI
https://doi.org/10.1039/B513768C
Article type
Communication
Submitted
29 Sep 2005
Accepted
28 Nov 2005
First published
21 Dec 2005

Chem. Commun., 2006, 621-623

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A molecular pinwheel multicopper(I) cluster, [(LS−)6CuI13(S2−)2]3+ with μ4-sulfido, μ3-thiolato and nitrogen ligands

Y. Lee, A. A. N. Sarjeant and K. D. Karlin, Chem. Commun., 2006, 621 DOI: 10.1039/B513768C

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