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Issue 8, 2006
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Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside

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Abstract

The regioselective and enantiospecific rhodium-catalyzed allylic amination of secondary allylic carbonates with N3-benzoyl thymine in conjunction with a stereoselective free radical cyclization provides a convenient method for the construction of a new conformationally rigid nucleoside.

Graphical abstract: Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside

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Publication details

The article was received on 15 Sep 2005, accepted on 22 Nov 2005, published on 13 Jan 2006 and first published online on 13 Jan 2006


Article type: Communication
DOI: 10.1039/B513083B
Citation: Chem. Commun., 2006, 844-846
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    Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside

    P. A. Evans, K. W. Lai, H. Zhang and J. C. Huffman, Chem. Commun., 2006, 844
    DOI: 10.1039/B513083B

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