Issue 8, 2006
From the journal:

Chemical Communications

Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside†

P. Andrew Evans,*a   Kwong Wah Lai,a   Hai-Ren Zhanga  and  John C. Huffman‡a  

* Corresponding authors

a Department of Chemistry, Indiana University, Bloomington, USA
E-mail: paevans@indiana.edu
Fax: (+1) 812-855-8300
Tel: (+1) 812-855-7368

Abstract

The regioselective and enantiospecific rhodium-catalyzed allylic amination of secondary allylic carbonates with N3-benzoyl thymine in conjunction with a stereoselective free radical cyclization provides a convenient method for the construction of a new conformationally rigid nucleoside.

Graphical abstract: Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside

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Article information

DOI
https://doi.org/10.1039/B513083B
Article type
Communication
Submitted
15 Sep 2005
Accepted
22 Nov 2005
First published
13 Jan 2006

Chem. Commun., 2006, 844-846

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Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside

P. A. Evans, K. W. Lai, H. Zhang and J. C. Huffman, Chem. Commun., 2006, 844 DOI: 10.1039/B513083B

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