Issue 44, 2005
From the journal:

Chemical Communications

A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12−: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10−†

Danielle Laurencin,a   Richard Villanneau,a   Patrick Herson,a   René Thouvenot,a   Yves Jeannina  and  Anna Proust*a  

* Corresponding authors

a Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR 7071, Université Pierre et Marie Curie, 4 Place Jussieu, Case courrier 42, Paris cedex 05, France
E-mail: proust@ccr.jussieu.fr

Abstract

The easy synthesis of [Sb2W20O70{Ru(p-cymene)}2]10− by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W20O70]14−, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)-substituted heteropolytungstates.

Graphical abstract: A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12−: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10−

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B510300B
Article type
Communication
Submitted
20 Jul 2005
Accepted
14 Sep 2005
First published
10 Oct 2005

Chem. Commun., 2005, 5524-5526

Permissions

Request permissions

A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12−: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10−

D. Laurencin, R. Villanneau, P. Herson, R. Thouvenot, Y. Jeannin and A. Proust, Chem. Commun., 2005, 5524 DOI: 10.1039/B510300B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements