Issue 44, 2005

A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12−: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10−

Abstract

The easy synthesis of [Sb2W20O70{Ru(p-cymene)}2]10− by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W20O70]14−, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)-substituted heteropolytungstates.

Graphical abstract: A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12−: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10−

Supplementary files

Article information

Article type
Communication
Submitted
20 Jul 2005
Accepted
14 Sep 2005
First published
10 Oct 2005

Chem. Commun., 2005, 5524-5526

A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12−: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10−

D. Laurencin, R. Villanneau, P. Herson, R. Thouvenot, Y. Jeannin and A. Proust, Chem. Commun., 2005, 5524 DOI: 10.1039/B510300B

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