Issue 40, 2005

Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

Abstract

Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni10(tmp)2(N3)8(acac)6(MeOH)6] leads to a spin ground state of S = 10; single crystal Mvs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.

Graphical abstract: Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2005
Accepted
17 Aug 2005
First published
13 Sep 2005

Chem. Commun., 2005, 5038-5040

Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

G. Aromí, S. Parsons, W. Wernsdorfer, E. K. Brechin and E. J. L. McInnes, Chem. Commun., 2005, 5038 DOI: 10.1039/B510097F

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