Issue 34, 2005
From the journal:

Chemical Communications

Zirconium mediated total synthesis of crinitol, 9-hydroxyfarnesoic acid, 9-hydroxyfarnesol, 9-hydroxysargaquinone and the selectively-protected aglycone of moritoside and euplexide A†

Sally Dixon,a   George J. Gordona  and  Richard J. Whitby*a  

* Corresponding authors

a School of Chemistry, University of Southampton, Highfield, Southampton, Hampshire, UK
E-mail: rjw1@soton.ac.uk
Fax: +44 (0) 2380593781
Tel: +44 (0)23 80592777

Abstract

Tandem formation of an unsaturated zirconacycle, insertion of methallyl carbenoid, and addition of an aldehyde provides a rapid synthetic route to several linear terpenoid and terpene–polyketide natural products.

Graphical abstract: Zirconium mediated total synthesis of crinitol, 9-hydroxyfarnesoic acid, 9-hydroxyfarnesol, 9-hydroxysargaquinone and the selectively-protected aglycone of moritoside and euplexide A

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Article information

DOI
https://doi.org/10.1039/B508524A
Article type
Communication
Submitted
16 Jun 2005
Accepted
14 Jul 2005
First published
05 Aug 2005

Chem. Commun., 2005, 4303-4305

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Zirconium mediated total synthesis of crinitol, 9-hydroxyfarnesoic acid, 9-hydroxyfarnesol, 9-hydroxysargaquinone and the selectively-protected aglycone of moritoside and euplexide A

S. Dixon, G. J. Gordon and R. J. Whitby, Chem. Commun., 2005, 4303 DOI: 10.1039/B508524A

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