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Issue 43, 2005
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Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η11-N2 complex and odd-electron organotrimetallic cluster

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Abstract

(C5Me5R)2Ta2Cl4 (d2–d2) disproportionates under dinitrogen to [(C5Me4R)TaCl2]2(μ-N2) and the D3h cluster cation (C5Me4R)3Ta3(μ-Cl)6+ with anionic (C5Me4R)TaCl4.

Graphical abstract: Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η1,η1-N2 complex and odd-electron organotrimetallic cluster

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Publication details

The article was received on 08 Jun 2005, accepted on 03 Aug 2005 and first published on 04 Oct 2005


Article type: Communication
DOI: 10.1039/B508148C
Citation: Chem. Commun., 2005,0, 5444-5446
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    Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η11-N2 complex and odd-electron organotrimetallic cluster

    T. Lee, A. J. Wooten, J. J. Luci, D. C. Swenson and L. Messerle, Chem. Commun., 2005, 0, 5444
    DOI: 10.1039/B508148C

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