Issue 34, 2005

High-nuclearity homometallic iron and nickel clusters: Fe22 and Ni24 complexes from the use of N-methyldiethanolamine

Abstract

The use of N-methyldiethanolamine (mdaH2) in reactions with Fe(III) and Ni(II) sources has led to Fe22 and Ni24 products; the clusters are the highest and second-highest, respectively, homometallic clusters for these metals to date, and possess S = 0 and S = 6 ground states, respectively.

Graphical abstract: High-nuclearity homometallic iron and nickel clusters: Fe22 and Ni24 complexes from the use of N-methyldiethanolamine

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2005
Accepted
11 Jul 2005
First published
03 Aug 2005

Chem. Commun., 2005, 4282-4284

High-nuclearity homometallic iron and nickel clusters: Fe22 and Ni24 complexes from the use of N-methyldiethanolamine

D. Foguet-Albiol, K. A. Abboud and G. Christou, Chem. Commun., 2005, 4282 DOI: 10.1039/B507748F

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